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Issue 44, 2017
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One-pot enyne metathesis/Diels–Alder/oxidation to six-membered silacycles with a multi-ring core: discovery of novel fluorophores

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Abstract

Polycyclic compounds containing a six-membered silacycle are important. However, we have limited knowledge of the nature of these six-membered silacycles because methodologies for their synthesis remain under-developed. Here, we have developed a one-pot enyne metathesis/Diels–Alder/oxidation methodology for the synthesis of six-membered silacycles. Some of these compounds are novel fluorophores.

Graphical abstract: One-pot enyne metathesis/Diels–Alder/oxidation to six-membered silacycles with a multi-ring core: discovery of novel fluorophores

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Publication details

The article was received on 11 Apr 2017, accepted on 26 Apr 2017 and first published on 26 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC02788E
Citation: Chem. Commun., 2017,53, 5970-5973
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    One-pot enyne metathesis/Diels–Alder/oxidation to six-membered silacycles with a multi-ring core: discovery of novel fluorophores

    S. Yoshioka, Y. Fujii, H. Tsujino, T. Uno, H. Fujioka and M. Arisawa, Chem. Commun., 2017, 53, 5970
    DOI: 10.1039/C7CC02788E

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