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Issue 53, 2017
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cis-Decalin oxidation as a stereochemical probe of in-MOF versus on-MOF catalysis

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Abstract

Development of catalyst-controlled C–H hydroxylation could provide direct access to valuable synthetic targets, such as primary metabolites. Here, we report a new family of porous materials, comprised of 2-dimensional metalloporphyrin layers and flexible aliphatic linkers, and demonstrate C–H hydroxylation activity. We demonstrate that the stereochemistry of cis-decalin oxidation provides a useful tool for differentiating catalysis in from catalysis on porous materials, which is critical to leveraging the potential of porous materials for catalyst-controlled oxidation chemistry.

Graphical abstract: cis-Decalin oxidation as a stereochemical probe of in-MOF versus on-MOF catalysis

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Publication details

The article was received on 04 Apr 2017, accepted on 07 Jun 2017 and first published on 07 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC02570J
Citation: Chem. Commun., 2017,53, 7377-7380
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    cis-Decalin oxidation as a stereochemical probe of in-MOF versus on-MOF catalysis

    A. D. Cardenal, H. Jeong Park, C. J. Chalker, K. G. Ortiz and D. C. Powers, Chem. Commun., 2017, 53, 7377
    DOI: 10.1039/C7CC02570J

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