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Reversible conversion between pleated oligo-Tetrathiafulvalene radical foldamer and folded donor-acceptor [3]pseudorotaxane under redox condition

Abstract

Linear tetrathiafulvalene (TTF) oligomers were synthesized, which could not only form pleated TTF radical cation foldamer under oxidation condition, but also interlocked with CBPQT4+ to form folded donor-acceptor [3]pseudorotaxane in the netrual state of TTF. Moreover, switchable transformation between these two folded supramolecular structures was achieved under the alternative regulation of the redox states of TTF units.

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Publication details

The article was received on 01 Apr 2017, accepted on 18 Apr 2017 and first published on 19 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC02526B
Citation: Chem. Commun., 2017, Accepted Manuscript
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    Reversible conversion between pleated oligo-Tetrathiafulvalene radical foldamer and folded donor-acceptor [3]pseudorotaxane under redox condition

    K. Zhang, T. Zhan, L. Wu, Z. Zhao, Z. Zhou, M. Yun, J. Wei, S. Zheng and H. Yin, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC02526B

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