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Issue 57, 2017
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A simple synthetic entryway into palladium cross-coupling catalysis

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Abstract

The simple synthesis of a family of palladates containing an imidazolium counterion is presented. These “ate” complexes can be easily converted into well-defined palladium–N-heterocyclic carbene (NHC) complexes. The synthetic protocols leading to the “ate” and to the Pd–NHC neutral complexes have been exemplified with various NHC ligands. The palladates prove efficient pre-catalysts enabling Suzuki–Miyaura and Mizoroki–Heck reactions.

Graphical abstract: A simple synthetic entryway into palladium cross-coupling catalysis

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Publication details

The article was received on 19 Apr 2017, accepted on 11 May 2017 and first published on 11 May 2017


Article type: Communication
DOI: 10.1039/C7CC02487H
Citation: Chem. Commun., 2017,53, 7990-7993
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    A simple synthetic entryway into palladium cross-coupling catalysis

    C. M. Zinser, F. Nahra, M. Brill, R. E. Meadows, D. B. Cordes, A. M. Z. Slawin, S. P. Nolan and C. S. J. Cazin, Chem. Commun., 2017, 53, 7990
    DOI: 10.1039/C7CC02487H

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