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A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

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Abstract

An apatite-type barium phosphate with a high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier Ueff of up to 387 cm−1, which is well above the values for all so far known d-metal based single-molecule magnets (SMMs).

Graphical abstract: A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

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Publication details

The article was received on 30 Mar 2017, accepted on 20 Apr 2017 and first published on 20 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC02453C
Citation: Chem. Commun., 2017, Advance Article
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    A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

    P. E. Kazin, M. A. Zykin, L. A. Trusov, A. A. Eliseev, O. V. Magdysyuk, R. E. Dinnebier, R. K. Kremer, C. Felser and M. Jansen, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC02453C

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