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Radical-carbene coupling reaction: Mn-catalyzed synthesis of indoles from aromatic amines and diazo compounds

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Abstract

An unprecedented coupling reaction between aromatic amines and diazo compounds was well developed, which afforded a bridge connecting between radical chemistry and metal carbene chemistry. This Mn-catalyzed tandem reaction also provided a fundamentally different and practical approach to the indole skeleton under mild conditions.

Graphical abstract: Radical-carbene coupling reaction: Mn-catalyzed synthesis of indoles from aromatic amines and diazo compounds

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Publication details

The article was received on 30 Mar 2017, accepted on 10 May 2017 and first published on 10 May 2017


Article type: Communication
DOI: 10.1039/C7CC02440A
Citation: Chem. Commun., 2017, Advance Article
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    Radical-carbene coupling reaction: Mn-catalyzed synthesis of indoles from aromatic amines and diazo compounds

    H. Li, Y. Zhao, L. Ma, M. Ma, J. Jiang and X. Wan, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC02440A

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