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Issue 56, 2017
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Aromatic stacking – a key step in nucleation

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Abstract

Crystal nucleation from solution is of central importance in the chemical and biological sciences. Linking nucleation kinetics to the properties of solutes and solvents remains a grand-challenge in physical chemistry. Through a unique dataset of compounds able to self-assemble via both hydrogen-bonds and aromatic stacking, we are able to compare the importance of these two types of interaction in driving the nucleation process. Contrary to previous reports in which solution chemistry and hydrogen bonding have been seen as controlling factors, we are now able to show that cluster growth via aromatic stacking holds the key.

Graphical abstract: Aromatic stacking – a key step in nucleation

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Publication details

The article was received on 29 Mar 2017, accepted on 22 Jun 2017 and first published on 22 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC02423A
Citation: Chem. Commun., 2017,53, 7905-7908
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    Aromatic stacking – a key step in nucleation

    A. J. Cruz-Cabeza, R. J. Davey, S. S. Sachithananthan, R. Smith, S. K. Tang, T. Vetter and Y. Xiao, Chem. Commun., 2017, 53, 7905
    DOI: 10.1039/C7CC02423A

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