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A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons

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Abstract

Selective O-borylation of silanols with diborons took place in the presence of Pd catalysts to give the corresponding boryl silyl ethers in high yields.

Graphical abstract: A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons

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Publication details

The article was received on 29 Mar 2017, accepted on 03 May 2017 and first published on 03 May 2017


Article type: Communication
DOI: 10.1039/C7CC02420G
Citation: Chem. Commun., 2017, Advance Article
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    A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons

    A. Yoshimura, M. Yoshinaga, H. Yamashita, M. Igarashi, S. Shimada and K. Sato, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC02420G

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