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Issue 40, 2017
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Asymmetric fluorinative dearomatization of tryptamine derivatives

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Abstract

An asymmetric fluorinative dearomatization reaction of tryptamine derivatives was developed by using a chiral anion phase transfer catalyst (PTC) system, and the preliminary results of the reaction mechanistic study were achieved. This method is characterized by a simple operation, facile introduction of a fluorine atom in a highly enantioselective manner and construction of two contiguous quaternary stereogenic centers.

Graphical abstract: Asymmetric fluorinative dearomatization of tryptamine derivatives

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Publication details

The article was received on 29 Mar 2017, accepted on 24 Apr 2017 and first published on 24 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC02419C
Citation: Chem. Commun., 2017,53, 5531-5534
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    Asymmetric fluorinative dearomatization of tryptamine derivatives

    X. Liang, C. Liu, W. Zhang and S. You, Chem. Commun., 2017, 53, 5531
    DOI: 10.1039/C7CC02419C

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