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Issue 46, 2017
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Copper(I)-mediated carboamination of vinyl azides by aryldiazonium salts: synthesis of N2-substituted 1,2,3-triazoles

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Abstract

A copper(I)-mediated carboamination cascade reaction between vinyl azides and aryldiazonium salts is described. Functionally diverse N2-substituted 1,2,3-triazoles were obtained in moderate to good yields through novel difunctionalization of vinyl azides by aryldiazonium salt sources. This method has a wide scope, good functional-group tolerance and insensitivity to an ambient atmosphere.

Graphical abstract: Copper(i)-mediated carboamination of vinyl azides by aryldiazonium salts: synthesis of N2-substituted 1,2,3-triazoles

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Publication details

The article was received on 29 Mar 2017, accepted on 18 May 2017 and first published on 18 May 2017


Article type: Communication
DOI: 10.1039/C7CC02391J
Citation: Chem. Commun., 2017,53, 6259-6262
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    Copper(I)-mediated carboamination of vinyl azides by aryldiazonium salts: synthesis of N2-substituted 1,2,3-triazoles

    Z. Liu, H. Ji, W. Gao, G. Zhu, L. Tong, F. Lei and B. Tang, Chem. Commun., 2017, 53, 6259
    DOI: 10.1039/C7CC02391J

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