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Copper(I)-Mediated Carboamination of Vinyl Azides by Aryldiazonium Salts: Synthesis of N2-substituted 1,2,3-Triazoles

Abstract

A copper(I)-mediated carboamination cascade reaction between vinyl azides and aryldiazonium salts is described. Functionally diverse N2-substituted 1,2,3-triazoles were yielded in moderate to good through novel difunctionalization of vinyl azides by aryldiazonium salt sources. This method has a wide scope, good functional-group tolerance and insensitivity to ambient atmosphere.

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Publication details

The article was received on 29 Mar 2017, accepted on 18 May 2017 and first published on 18 May 2017


Article type: Communication
DOI: 10.1039/C7CC02391J
Citation: Chem. Commun., 2017, Accepted Manuscript
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    Copper(I)-Mediated Carboamination of Vinyl Azides by Aryldiazonium Salts: Synthesis of N2-substituted 1,2,3-Triazoles

    Z. Liu, H. Ji, W. Gao, G. Zhu, L. Tong, F. Lei and B. Tang, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC02391J

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