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Highly efficient Tsuji–Trost allylation in water catalyzed by Pd-nanoparticles

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Abstract

Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji–Trost allylations in water with very high turnover numbers. The di-allylation of methylene active compounds and the allylation of bio-based phenols was performed in high yield. The allylation of lignin showed a high selectivity towards the phenolic OH groups.

Graphical abstract: Highly efficient Tsuji–Trost allylation in water catalyzed by Pd-nanoparticles

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Publication details

The article was received on 28 Mar 2017, accepted on 18 Apr 2017 and first published on 18 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC02380D
Citation: Chem. Commun., 2017, Advance Article
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    Highly efficient Tsuji–Trost allylation in water catalyzed by Pd-nanoparticles

    A. Llevot, B. Monney, A. Sehlinger, S. Behrens and M. A. R. Meier, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC02380D

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