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Rhodium-catalyzed addition of sulfonyl hydrazides to allenes: regioselective synthesis of branched allylic sulfones

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Abstract

A rhodium-catalyzed regioselective addition of sulfonyl hydrazides to allenes is reported. With Rh(I)/DPEphos/benzoic acid as the catalyst system, branched allylic sulfones can be obtained, in good to excellent yields and regioselectivities.

Graphical abstract: Rhodium-catalyzed addition of sulfonyl hydrazides to allenes: regioselective synthesis of branched allylic sulfones

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Publication details

The article was received on 28 Mar 2017, accepted on 07 Apr 2017 and first published on 07 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC02375H
Citation: Chem. Commun., 2017, Advance Article
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    Rhodium-catalyzed addition of sulfonyl hydrazides to allenes: regioselective synthesis of branched allylic sulfones

    V. Khakyzadeh, Y. Wang and B. Breit, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC02375H

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