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Donor ligands based on tricoordinate boron formed by B–H-activation of bis(phosphine)boronium salts

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Abstract

We report a novel method for the preparation of PBP-pincer complexes from bis(phosphine)boronium salts. The central (R3P)2HB-moiety in a palladium complex is demonstrated to be a L-type ligand, therewith completing a series of pincer-type complexes with Z-, X- and L-type boron-based ligands, respectively.

Graphical abstract: Donor ligands based on tricoordinate boron formed by B–H-activation of bis(phosphine)boronium salts

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Publication details

The article was received on 27 Mar 2017, accepted on 27 Apr 2017 and first published on 27 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC02335A
Citation: Chem. Commun., 2017, Advance Article
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    Donor ligands based on tricoordinate boron formed by B–H-activation of bis(phosphine)boronium salts

    M. Grätz, A. Bäcker, L. Vondung, L. Maser, A. Reincke and R. Langer, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC02335A

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