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Issue 40, 2017
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Stable (sila)difluoromethylboranes via C–F activation of fluoroform derivatives

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Abstract

Lithium 1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaborol-2-uide activates the C–F linkage of fluoroform (CF3H) and the Ruppert–Prakash reagent (CF3SiMe3) to provide difluoromethyl-substituted boranes as air-stable compounds.

Graphical abstract: Stable (sila)difluoromethylboranes via C–F activation of fluoroform derivatives

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Publication details

The article was received on 27 Mar 2017, accepted on 21 Apr 2017 and first published on 21 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC02327H
Citation: Chem. Commun., 2017,53, 5546-5548
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    Stable (sila)difluoromethylboranes via C–F activation of fluoroform derivatives

    S. Ito, N. Kato and K. Mikami, Chem. Commun., 2017, 53, 5546
    DOI: 10.1039/C7CC02327H

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