Issue 33, 2017

Benz-amidinato calcium iodide catalyzed aldehyde and ketone hydroboration with unprecedented functional group tolerance

Abstract

A benz-amidinato calcium compound, [PhC(NiPr)2CaI] (1), catalyzed hydroboration of a wide range of aldehydes and ketones using pinacolborane (HBpin) at room temperature is reported. The catalyst shows functional group tolerance even towards OH and NH groups. The strategy was further extended to imines.

Graphical abstract: Benz-amidinato calcium iodide catalyzed aldehyde and ketone hydroboration with unprecedented functional group tolerance

Supplementary files

Article information

Article type
Communication
Submitted
27 Mar 2017
Accepted
30 Mar 2017
First published
31 Mar 2017

Chem. Commun., 2017,53, 4562-4564

Benz-amidinato calcium iodide catalyzed aldehyde and ketone hydroboration with unprecedented functional group tolerance

S. Yadav, S. Pahar and S. S. Sen, Chem. Commun., 2017, 53, 4562 DOI: 10.1039/C7CC02311A

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