Issue 53, 2017
From the journal:

Chemical Communications

Gram-scale free radical polymerization of an azaborine vinyl monomer†

Heidi L. van de Wouw, ORCID logo ‡a   Jae Young Lee ORCID logo ‡a  and  Rebekka S. Klausen ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Johns Hopkins University, 3400 N. Charles St, Baltimore, MD 21218, USA
E-mail: klausen@jhu.edu

Abstract

The gram-scale polymerization of a novel azaborine vinyl monomer is reported. We describe an efficient and high-yielding synthesis of B-vinyl-2,1-borazanaphthalene. Homopolymers and co-polymers with 2-vinylnaphthalene are characterized by heteronuclear NMR and absorbance spectroscopy.

Graphical abstract: Gram-scale free radical polymerization of an azaborine vinyl monomer

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Article information

DOI
https://doi.org/10.1039/C7CC02300F
Article type
Communication
Submitted
26 Mar 2017
Accepted
30 May 2017
First published
30 May 2017

Chem. Commun., 2017,53, 7262-7265

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Gram-scale free radical polymerization of an azaborine vinyl monomer

H. L. van de Wouw, J. Y. Lee and R. S. Klausen, Chem. Commun., 2017, 53, 7262 DOI: 10.1039/C7CC02300F

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