Issue 44, 2017
From the journal:

Chemical Communications

Hybrid ultramicroporous materials (HUMs) with enhanced stability and trace carbon capture performance†

Amrit Kumar,‡a   Carol Hua,‡a   David G. Madden, ORCID logo a   Daniel O’Nolan,a   Kai-Jie Chen,a   Lee-Ann J. Keane,a   John J. Perry, IV ORCID logo a  and  Michael J. Zaworotko ORCID logo *a  

* Corresponding authors

a Bernal Institute, Department of Chemical Sciences, University of Limerick, Limerick, Republic of Ireland
E-mail: xtal@ul.ie

Abstract

Fine-tuning of HUMs through pillar substitution can significantly enhance trace CO2 sorption performance and stability. The resulting materials, exemplified by the new material TIFSIX-3-Ni, [Ni(pyrazine)2(TiF6)]n, are shown through temperature programmed desorption experiments to remove trace quantities of CO2 from moist gas mixtures.

Graphical abstract: Hybrid ultramicroporous materials (HUMs) with enhanced stability and trace carbon capture performance

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Article information

DOI
https://doi.org/10.1039/C7CC02289A
Article type
Communication
Submitted
26 Mar 2017
Accepted
21 Apr 2017
First published
21 Apr 2017

Chem. Commun., 2017,53, 5946-5949

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Hybrid ultramicroporous materials (HUMs) with enhanced stability and trace carbon capture performance

A. Kumar, C. Hua, D. G. Madden, D. O’Nolan, K. Chen, L. J. Keane, J. J. Perry and M. J. Zaworotko, Chem. Commun., 2017, 53, 5946 DOI: 10.1039/C7CC02289A

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