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Efficient synthesis of cyclic P-stereogenic phosphinamides from acyclic chiral precursors via radical oxidative intramolecular aryl C–H phosphinamidation

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Abstract

We present a highly efficient method for the synthesis of cyclic P-stereogenic phosphinamides via the Ce(IV)-promoted radical oxidative aryl C–H phosphinamidation of acyclic P-stereogenic phosphinamides. The new protocol provides a useful platform for the versatile synthesis of various potentially useful P-stereogenic compounds.

Graphical abstract: Efficient synthesis of cyclic P-stereogenic phosphinamides from acyclic chiral precursors via radical oxidative intramolecular aryl C–H phosphinamidation

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Publication details

The article was received on 25 Mar 2017, accepted on 03 May 2017 and first published on 04 May 2017


Article type: Communication
DOI: 10.1039/C7CC02263H
Citation: Chem. Commun., 2017, Advance Article
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    Efficient synthesis of cyclic P-stereogenic phosphinamides from acyclic chiral precursors via radical oxidative intramolecular aryl C–H phosphinamidation

    Y. Chen, X. Qin and F. Han, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC02263H

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