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Issue 35, 2017
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A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring

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Abstract

The adiabatic temperature change of the star-shaped {CoIII3GdIII3} magnetocaloric ring is enhanced via topological control over the assembly process, by using a pre-formed {CoII(H6L)} building block that undergoes oxidation to CoIII, successfully separating the GdIII ions.

Graphical abstract: A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring

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Publication details

The article was received on 24 Mar 2017, accepted on 05 Apr 2017 and first published on 13 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC02243C
Citation: Chem. Commun., 2017,53, 4799-4802
  • Open access: Creative Commons BY license
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    A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring

    M. J. H. Ojea, G. Lorusso, G. A. Craig, C. Wilson, M. Evangelisti and M. Murrie, Chem. Commun., 2017, 53, 4799
    DOI: 10.1039/C7CC02243C

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