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Cooperative Carbon Monoxide to Formyl Reduction at a Trifunctional PBB Frustrated Lewis Pair

Abstract

Twofold hydroboration of the bulky Mes*P(vinyl)2 phosphane with Piers’ borane [HB(C6F5)2] followed by C6F5 / H exchange with 9-BBN generated a reactive P/B/BH FLP structure that cleanly reduced carbon-monoxide at the trifunctional frustrated Lewis pair framework to the [B]-formyl stage.

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Publication details

The article was accepted on 12 Apr 2017 and first published on 13 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC02214J
Citation: Chem. Commun., 2017, Accepted Manuscript
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    Cooperative Carbon Monoxide to Formyl Reduction at a Trifunctional PBB Frustrated Lewis Pair

    G. Kehr, L. Wang, C. G. Daniliuc, G. Erker, S. Zhang and Y. Hasegawa, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC02214J

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