Jump to main content
Jump to site search


An organolanthanide(III) single-molecule magnet with an axial crystal-field: influence of the Raman process over the slow relaxation

Author affiliations

Abstract

Here, we report the synthesis and magnetic properties investigation of a series of new organometallic homoleptic complexes Li(DME)3[Ln(DAD)2] (Ln = Dy (1a, 1b), Tb(2), and Er(3)) based on paramagnetic Ln(III) ions coordinated by an ene-diamido[2,6-iPr2C6H3N–CH[double bond, length as m-dash]CH–NC6H3iPr2-2,6]2− (DAD) ligand. Dy-based compounds exhibit a genuine single-molecule magnet (SMM) behaviour, while the Tb3+ analogue shows a field-induced slow relaxation of the magnetisation.

Graphical abstract: An organolanthanide(iii) single-molecule magnet with an axial crystal-field: influence of the Raman process over the slow relaxation

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 09 Feb 2017, accepted on 01 Apr 2017 and first published on 04 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC02213A
Citation: Chem. Commun., 2017, Advance Article
  •   Request permissions

    An organolanthanide(III) single-molecule magnet with an axial crystal-field: influence of the Raman process over the slow relaxation

    J. Long, B. G. Shestakov, D. Liu, L. F. Chibotaru, Y. Guari, A. V. Cherkasov, G. K. Fukin, A. A. Trifonov and J. Larionova, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC02213A

Search articles by author