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Issue 56, 2017
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Monodispersed gold nanoparticles supported on a zirconium-based porous metal–organic framework and their high catalytic ability for the reverse water–gas shift reaction

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Abstract

A highly active and selective Au@UIO-67 catalyst has been assembled. Gold nanoparticles (AuNPs) are monodispersed on the UIO-67 surface of a porous metal–organic framework, the micropores in UIO-67 as templates for adsorbing Au ions and enhancing interaction between AuNPs and UIO-67, favoring the formation of isolated and well-dispersed AuNPs. The catalyst exhibits high catalytic activity and CO selectivity for the reverse water–gas shift reaction in a fixed-bed flow reactor.

Graphical abstract: Monodispersed gold nanoparticles supported on a zirconium-based porous metal–organic framework and their high catalytic ability for the reverse water–gas shift reaction

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Publication details

The article was received on 21 Mar 2017, accepted on 16 Jun 2017 and first published on 16 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC02130E
Citation: Chem. Commun., 2017,53, 7953-7956
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    Monodispersed gold nanoparticles supported on a zirconium-based porous metal–organic framework and their high catalytic ability for the reverse water–gas shift reaction

    H. Xu, Y. Li, X. Luo, Z. Xu and J. Ge, Chem. Commun., 2017, 53, 7953
    DOI: 10.1039/C7CC02130E

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