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Issue 44, 2017
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3,4-Alkadienyl ketones via the palladium-catalyzed decarboxylative allenylation of 3-oxocarboxylic acids

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Abstract

In this communication, we report a palladium-catalyzed decarboxylative allenylation of benzyl carbonates and tert-butyl carbonates of 2,3-allenols with 3-oxocarboxylic acids. The reaction provides a new and straightforward approach to 3,4-dienyl ketones under mild conditions.

Graphical abstract: 3,4-Alkadienyl ketones via the palladium-catalyzed decarboxylative allenylation of 3-oxocarboxylic acids

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Publication details

The article was received on 17 Mar 2017, accepted on 02 May 2017 and first published on 02 May 2017


Article type: Communication
DOI: 10.1039/C7CC02050C
Citation: Chem. Commun., 2017,53, 6037-6040
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    3,4-Alkadienyl ketones via the palladium-catalyzed decarboxylative allenylation of 3-oxocarboxylic acids

    T. Zhu and S. Ma, Chem. Commun., 2017, 53, 6037
    DOI: 10.1039/C7CC02050C

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