Issue 45, 2017
From the journal:

Chemical Communications

Metallocorroles as inherently chiral chromophores: resolution and electronic circular dichroism spectroscopy of a tungsten biscorrole†‡

Christine Schies,a   Abraham B. Alemayehu,b   Hugo Vazquez-Lima,b   Kolle E. Thomas,b   Torsten Bruhn, ORCID logo *ac   Gerhard Bringmann ORCID logo *a  and  Abhik Ghosh ORCID logo *b  

* Corresponding authors

a Institute of Organic Chemistry, University of Würzburg, 97074 Würzburg, Germany
E-mail: bringman@chemie.uni-wuerzburg.de

b Department of Chemistry and Center for Theoretical and Computational Chemistry, UiT – The Arctic University of Norway, 9037 Tromsø, Norway
E-mail: abhik.ghosh@uit.no

c Federal Institute of Risk Assessment, 14979 Berlin, Germany
E-mail: torsten.bruhn@bfr.bund.de

Abstract

An inherently chiral metallocorrole has been resolved for the first time by means of HPLC on a chiral stationary phase. For the compound in question, a homoleptic tungsten biscorrole, the absolute configurations of the enantiomers were assigned using online HPLC–ECD measurements in conjunction with time-dependent CAM-B3LYP calculations, which provided accurate simulations of the ECD spectra.

Graphical abstract: Metallocorroles as inherently chiral chromophores: resolution and electronic circular dichroism spectroscopy of a tungsten biscorrole

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Article information

DOI
https://doi.org/10.1039/C7CC02027A
Article type
Communication
Submitted
16 Mar 2017
Accepted
15 May 2017
First published
22 May 2017

Chem. Commun., 2017,53, 6121-6124

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Metallocorroles as inherently chiral chromophores: resolution and electronic circular dichroism spectroscopy of a tungsten biscorrole

C. Schies, A. B. Alemayehu, H. Vazquez-Lima, K. E. Thomas, T. Bruhn, G. Bringmann and A. Ghosh, Chem. Commun., 2017, 53, 6121 DOI: 10.1039/C7CC02027A

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