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Three-component nanorotors generated from fusion of complexes and post-fusion metal–metal exchange

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Abstract

The fusion of two homoleptic complexes quantitatively created a novel three-component nanorotor. The intra-supramolecular rotational dynamics leads to a rapid exchange (k298 = 24.0 ± 2.5 kHz) of two degenerate Npy → ZnPor interactions. Metal exchange at the remote HETTAP complexation site provided a faster nanorotor (k298 = 34.0 ± 3.0 kHz).

Graphical abstract: Three-component nanorotors generated from fusion of complexes and post-fusion metal–metal exchange

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Publication details

The article was received on 15 Mar 2017, accepted on 15 Apr 2017 and first published on 18 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC01977G
Citation: Chem. Commun., 2017, Advance Article
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    Three-component nanorotors generated from fusion of complexes and post-fusion metal–metal exchange

    A. Goswami, I. Paul and M. Schmittel, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01977G

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