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Three-Component Nanorotors Generated from Fusion of Complexes and Post-Fusion Metal-Metal Exchange

Abstract

The fusion of two homoleptic complexes quantitatively created a novel three-component nanorotor. The intra-supramolecular rotational dynamics leads to a rapid exchange (k298 = 24.0 ± 2.5 kHz) of two degenerate Npy --> ZnPor interactions. Metal exchange at the remote HETTAP complexation site provided a faster nanorotor (k298 = 34.0 ± 3.0 kHz).

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Publication details

The article was received on 15 Mar 2017, accepted on 15 Apr 2017 and first published on 18 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC01977G
Citation: Chem. Commun., 2017, Accepted Manuscript
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    Three-Component Nanorotors Generated from Fusion of Complexes and Post-Fusion Metal-Metal Exchange

    M. Schmittel, A. Goswami and I. Paul, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC01977G

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