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Issue 36, 2017
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Spin-state modulation of molecular FeIII complexes via inclusion in halogen-bonded supramolecular networks

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Abstract

The cationic complex [Fe(qsal)2]+ (Hqsal = N-(8-quinolyl)salicylaldimine) is encapsulated in anionic halogen-bonded 1D and 2D networks derived from sym-triiodotrifluorobenzene, [(C6F3I3)Cl] and [(C6F3I3)I]. Structural analysis and magnetic measurements show that the spin-state of this complex can be modulated by its inclusion in supramolecular host frameworks.

Graphical abstract: Spin-state modulation of molecular FeIII complexes via inclusion in halogen-bonded supramolecular networks

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Publication details

The article was received on 14 Mar 2017, accepted on 31 Mar 2017 and first published on 31 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01943B
Citation: Chem. Commun., 2017,53, 4989-4992
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    Spin-state modulation of molecular FeIII complexes via inclusion in halogen-bonded supramolecular networks

    I. Jeon, O. Jeannin, R. Clérac, M. Rouzières and M. Fourmigué, Chem. Commun., 2017, 53, 4989
    DOI: 10.1039/C7CC01943B

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