Ionic liquid/H2O-mediated synthesis of mesoporous organic polymers and their application in methylation of amines

Xiaoxiao Yu; Zhenzhen Yang; Hongye Zhang; Bo Yu; Yanfei Zhao; Zhenghui Liu; Guipeng Ji; Zhimin Liu

doi:10.1039/C7CC01910F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Ionic liquid/H₂O-mediated synthesis of mesoporous organic polymers and their application in methylation of amines†

Xiaoxiao Yu,‡^ab Zhenzhen Yang,‡^a Hongye Zhang,^a Bo Yu,^a Yanfei Zhao,^a Zhenghui Liu,^ab Guipeng Ji^ab and Zhimin Liu

*^ab

Author affiliations

* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: liuzm@iccas.ac.cn

^b University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Mesoporous Tröger's base-functionalized polymers (Meso-TBPs) were prepared using a sulfonic acid group functionalized ionic liquid/H₂O system, with surface areas up to 431 m² g⁻¹ and pore sizes of 3–15 nm. Ir(II) coordinated Meso-TBPs exhibited extraordinary catalytic performance in the N-methylation of amines using methanol.

Download options Please wait...

Supplementary files

Supplementary information PDF (4715K)

Article information

DOI: https://doi.org/10.1039/C7CC01910F
Article type: Communication
Submitted: 13 Mar 2017
Accepted: 04 May 2017
First published: 04 May 2017

Download Citation

Chem. Commun., 2017,53, 5962-5965

Permissions

Request permissions

Ionic liquid/H₂O-mediated synthesis of mesoporous organic polymers and their application in methylation of amines

X. Yu, Z. Yang, H. Zhang, B. Yu, Y. Zhao, Z. Liu, G. Ji and Z. Liu, Chem. Commun., 2017, 53, 5962 DOI: 10.1039/C7CC01910F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications