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Thermal spin-crossover with a large hysteresis spanning room temperature in a mononuclear complex

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Abstract

A large hysteresis centered around room temperature represents one of the mandatory goals of research on functional switchable materials. In the thoroughly studied field of spin-crossover, such behaviour appears very rarely and essentially concerns coordination networks. A new compound showing a large spin-crossover hysteresis spanning room temperature demonstrates in a definitive manner that this goal is achievable in molecular discrete compounds without damaging the single-crystal character.

Graphical abstract: Thermal spin-crossover with a large hysteresis spanning room temperature in a mononuclear complex

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Publication details

The article was received on 09 Mar 2017, accepted on 22 Mar 2017 and first published on 22 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01806A
Citation: Chem. Commun., 2017, Advance Article
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    Thermal spin-crossover with a large hysteresis spanning room temperature in a mononuclear complex

    E. Tailleur, M. Marchivie, N. Daro, G. Chastanet and P. Guionneau, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01806A

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