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Photoisomerisation and light-induced morphological switching of a polyoxometalate–azobenzene hybrid

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Abstract

The functionalization of a spherical Keplerate-type polyoxometalate {Mo72V30} with a cationic azobenzene surfactant has been achieved through ionic self-assembly. The photoisomerisation reaction of this complex, which emerges in a light-triggered aggregation–disaggregation process, has been followed by 1H NMR spectroscopy, dynamic light scattering, absorption spectroscopy and scanning electron microscopy analyses.

Graphical abstract: Photoisomerisation and light-induced morphological switching of a polyoxometalate–azobenzene hybrid

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Publication details

The article was received on 09 Mar 2017, accepted on 10 Apr 2017 and first published on 10 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC01805C
Citation: Chem. Commun., 2017, Advance Article
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    Photoisomerisation and light-induced morphological switching of a polyoxometalate–azobenzene hybrid

    G. Markiewicz, D. Pakulski, A. Galanti, V. Patroniak, A. Ciesielski, A. R. Stefankiewicz and P. Samorì, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01805C

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