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Issue 36, 2017
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A highly efficient Cu catalyst system for the radical reactions of α-bromocarbonyls

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Abstract

In this communication, we established highly efficient Cu-catalyzed ARGET-ATRS (atom-transfer radical substitution) of alpha-bromocarbonyls with styrenes to produce tert-alkylated styrenes. The maximum TON was up to 12 000. Hünig's base was very important to regenerate active CuI. Moreover, a Cu-catalyzed C–C cleavage reaction via SH2′ and intermolecular C–H cyclization of α-bromoimide was found.

Graphical abstract: A highly efficient Cu catalyst system for the radical reactions of α-bromocarbonyls

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Publication details

The article was received on 09 Mar 2017, accepted on 13 Apr 2017 and first published on 13 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC01790A
Citation: Chem. Commun., 2017,53, 5017-5019
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    A highly efficient Cu catalyst system for the radical reactions of α-bromocarbonyls

    Y. Noda and T. Nishikata, Chem. Commun., 2017, 53, 5017
    DOI: 10.1039/C7CC01790A

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