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Issue 55, 2017
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[(CH3)3PCH2OH][CdBr3] is a perovskite-type ferroelastic compound above room temperature

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Abstract

A new organic–inorganic perovskite-type compound [(CH3)3PCH2OH][CdBr3] exhibits a ferroelastic phase transition at 339 K. Domain structures were observed and analyzed. The origin of the phase transition can be attributed to the motion or reorientation of the [(CH3)3PCH2OH]+ cations and the displacement of Cd2+ and Br ions in solid-state crystals.

Graphical abstract: [(CH3)3PCH2OH][CdBr3] is a perovskite-type ferroelastic compound above room temperature

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Publication details

The article was received on 08 Mar 2017, accepted on 13 Jun 2017 and first published on 14 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC01771E
Citation: Chem. Commun., 2017,53, 7756-7759
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    [(CH3)3PCH2OH][CdBr3] is a perovskite-type ferroelastic compound above room temperature

    X. Zheng, L. Zhou, P. Shi, F. Geng, D. Fu and Q. Ye, Chem. Commun., 2017, 53, 7756
    DOI: 10.1039/C7CC01771E

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