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[(CH3)3PCH2OH][CdBr3] Is a Perovskite-type Ferroelastic Compound Above Room Temperature

Abstract

A new organic-inorganic perovskite-type compound [(CH3)3PCH2OH][CdBr3] exhibits a ferroelastic phase transition at 339 K. Domain structures were observed and analyzed. The origin of the phase transition can be attributed to the motion or reorientation of the [(CH3)3PCH2OH]+ cations and the displacement of Cd2+ and Br- ions in solid-state crystal.

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Publication details

The article was received on 08 Mar 2017, accepted on 13 Jun 2017 and first published on 14 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC01771E
Citation: Chem. Commun., 2017, Accepted Manuscript
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    [(CH3)3PCH2OH][CdBr3] Is a Perovskite-type Ferroelastic Compound Above Room Temperature

    X. Zheng, L. Zhou, P. Shi, F. Geng, D. Fu and Q. Ye, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC01771E

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