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Diversification reactions of γ-silyl allenyl esters: selective conversion to all-carbon quaternary centers and γ-allene dicarbinols

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Abstract

The unique reactivity of γ-silyl allenyl esters is described. Taking advantage of the silyl group as a fluoride acceptor, these allenoates readily underwent addition to a variety of electrophiles to selectively yield products with all-carbon quaternary centers or allenoate dicarbinols. These dicarbinols were subsequently converted to novel highly substituted 6-hydro-2-pyrones.

Graphical abstract: Diversification reactions of γ-silyl allenyl esters: selective conversion to all-carbon quaternary centers and γ-allene dicarbinols

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Publication details

The article was received on 06 Mar 2017, accepted on 06 Apr 2017 and first published on 11 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC01708A
Citation: Chem. Commun., 2017, Advance Article
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    Diversification reactions of γ-silyl allenyl esters: selective conversion to all-carbon quaternary centers and γ-allene dicarbinols

    S. Jana, A. Roy and S. D. Lepore, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01708A

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