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Issue 36, 2017
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Synthesis and characterization of a dipyriamethyrin–uranyl complex

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Abstract

The reaction between non-aqueous uranyl silylamide (UO2[N(SiMe3)2]2·2THF) under anaerobic conditions or uranyl acetate (UO2(OAc)2·2H2O) under standard laboratory conditions and dipyriamethryin affords a bench-stable uranyl complex. Competition studies as well as DFT calculations provide support for the observed selectivity for the uranyl cation over trivalent lanthanide and multiple transition metal precursors.

Graphical abstract: Synthesis and characterization of a dipyriamethyrin–uranyl complex

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Publication details

The article was received on 03 Mar 2017, accepted on 10 Apr 2017 and first published on 12 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC01674C
Citation: Chem. Commun., 2017,53, 4981-4984
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    Synthesis and characterization of a dipyriamethyrin–uranyl complex

    J. T. Brewster, Q. He, G. Anguera, M. D. Moore, X. Ke, V. M. Lynch and J. L. Sessler, Chem. Commun., 2017, 53, 4981
    DOI: 10.1039/C7CC01674C

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