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Conjunctive functionalization of vinyl boronate complexes with electrophiles: a diastereoselective three-component coupling

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Abstract

A method for the conjunctive functionalization of vinyl boronate complexes with electrophiles is described. The overall process represents a three-component coupling between a vinyl boronic ester, carbon nucleophile and an electrophile, thus affording complex multifunctionalized products from simple starting materials. The diastereoselectivity (syn or anti) of this process is strongly dependent upon the nature of the electrophile.

Graphical abstract: Conjunctive functionalization of vinyl boronate complexes with electrophiles: a diastereoselective three-component coupling

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Publication details

The article was received on 03 Mar 2017, accepted on 07 Apr 2017 and first published on 20 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC01671A
Citation: Chem. Commun., 2017, Advance Article
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    Conjunctive functionalization of vinyl boronate complexes with electrophiles: a diastereoselective three-component coupling

    R. J. Armstrong, C. Sandford, C. García-Ruiz and V. K. Aggarwal, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01671A

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