Jump to main content
Jump to site search


Difluoromethylcarbene for iron-catalyzed cyclopropanation

Author affiliations

Abstract

Difluoroethylsulfonium salt, Ph2S+CH2CF2H OTf, was developed into a convenient difluoromethylcarbene reagent for the iron-catalyzed cyclopropanation of terminal olefins, giving various difluoromethyl–cyclopropanes with excellent diastereoselectivities and in high yields.

Graphical abstract: Difluoromethylcarbene for iron-catalyzed cyclopropanation

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 02 Mar 2017, accepted on 13 Mar 2017, published on 13 Mar 2017 and first published online on 13 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01636K
Citation: Chem. Commun., 2017, Advance Article
  •   Request permissions

    Difluoromethylcarbene for iron-catalyzed cyclopropanation

    Y. Duan, J. Lin, J. Xiao and Y. Gu, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01636K

Search articles by author