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Kinetic resolution via supramolecular iminium catalysis: multiactivation enables the asymmetric synthesis of β-aryl substituted aldehydes and densely functionalized cyclohexanes

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Abstract

The kinetic resolution of β-aryl substituted 1,7-dioxo compounds with α,β-unsaturated aldehydes affording enantioenriched β-aryl substituted aldehydes as well as densely functionalized cyclohexanes is presented. The two enantioenriched products were obtained in reasonable yields with high diastereo- and enantioselectivities under supramolecular iminium catalysis which activates both the substrates and the reactive intermediates.

Graphical abstract: Kinetic resolution via supramolecular iminium catalysis: multiactivation enables the asymmetric synthesis of β-aryl substituted aldehydes and densely functionalized cyclohexanes

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Publication details

The article was received on 02 Mar 2017, accepted on 31 Mar 2017 and first published on 31 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01625E
Citation: Chem. Commun., 2017, Advance Article
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    Kinetic resolution via supramolecular iminium catalysis: multiactivation enables the asymmetric synthesis of β-aryl substituted aldehydes and densely functionalized cyclohexanes

    Z. Jia, Y. Wang, G. Xu and P. Xu, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01625E

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