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Selective perrhenate recognition in pure water by halogen bonding and hydrogen bonding alpha-cyclodextrin based receptors

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Abstract

Alpha-cyclodextrin based anion receptors functionalised with pendant arms containing halogen and hydrogen bond donor motifs display selective association of perrhenate in aqueous media at neutral pH. NMR and ITC anion binding investigations reveal the halogen bonding receptor to be the superior host.

Graphical abstract: Selective perrhenate recognition in pure water by halogen bonding and hydrogen bonding alpha-cyclodextrin based receptors

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Publication details

The article was received on 01 Mar 2017, accepted on 14 Mar 2017, published on 15 Mar 2017 and first published online on 15 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01605K
Citation: Chem. Commun., 2017, Advance Article
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    Selective perrhenate recognition in pure water by halogen bonding and hydrogen bonding alpha-cyclodextrin based receptors

    S. P. Cornes, M. R. Sambrook and P. D. Beer, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01605K

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