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Issue 40, 2017
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Electrosynthesis of NiPx nanospheres for electrocatalytic hydrogen evolution from a neutral aqueous solution

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Abstract

Due to the “ligand effect” and “ensemble effect”, incorporating phosphorus into nickel metal is a promising strategy to prepare an electrocatalyst for the hydrogen evolution reaction (HER). Herein, uniform NiPx nanospheres are deposited on electrode substrates by a simple and fast electrosynthesis method. As expected, the NiPx nanospheres can act as an excellent HER catalyst in a neutral buffer solution. It requires a low overpotential of 230 mV to achieve a current density of 10 mA cm−2, and the stability has been proven to be outstanding by long-term electrolysis.

Graphical abstract: Electrosynthesis of NiPx nanospheres for electrocatalytic hydrogen evolution from a neutral aqueous solution

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Publication details

The article was received on 01 Mar 2017, accepted on 11 Apr 2017 and first published on 12 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC01584D
Citation: Chem. Commun., 2017,53, 5507-5510
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    Electrosynthesis of NiPx nanospheres for electrocatalytic hydrogen evolution from a neutral aqueous solution

    M. Chen, J. Qi, W. Zhang and R. Cao, Chem. Commun., 2017, 53, 5507
    DOI: 10.1039/C7CC01584D

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