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Issue 43, 2017
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Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles

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Abstract

The homoleptic sandwich compounds – Mo and W biscorroles – have afforded a novel platform for experimental studies of relativistic effects. A 200 mV difference in reduction potential and a remarkable 130 nm shift of a near-IR spectral feature have been identified as manifestations of relativistic effects on the properties of these complexes.

Graphical abstract: Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles

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Publication details

The article was received on 28 Feb 2017, accepted on 08 May 2017 and first published on 12 May 2017


Article type: Communication
DOI: 10.1039/C7CC01549F
Citation: Chem. Commun., 2017,53, 5830-5833
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    Relativistic effects in metallocorroles: comparison of molybdenum and tungsten biscorroles

    A. B. Alemayehu, H. Vazquez-Lima, L. J. McCormick and A. Ghosh, Chem. Commun., 2017, 53, 5830
    DOI: 10.1039/C7CC01549F

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