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Issue 28, 2017
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H2O-Improved O2 activation on the Pd–Au bimetallic surface

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Abstract

Improved activation of adsorbed O2 by co-adsorbed H2O on the Pd–Au(111) surface has been observed. When co-adsorbed with H2O, O2 admolecules on the Pd–Au surface are more strongly bound via their interactions with H2O. This interaction leads to large enhancements in the dissociation of O2 as determined via the generation of CO2 upon exposure to CO.

Graphical abstract: H2O-Improved O2 activation on the Pd–Au bimetallic surface

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Publication details

The article was received on 28 Feb 2017, accepted on 16 Mar 2017 and first published on 16 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01542A
Citation: Chem. Commun., 2017,53, 3990-3993
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    H2O-Improved O2 activation on the Pd–Au bimetallic surface

    S. Han, E. J. Evans, G. M. Mullen and C. B. Mullins, Chem. Commun., 2017, 53, 3990
    DOI: 10.1039/C7CC01542A

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