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Reversible dinitrogen binding to [Cp′Fe(NHC)] associated with an N2-induced spin state change

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Abstract

The 15-valence electron (VE), high-spin (S = 3/2) half-sandwich complex [Cp′Fe(IiPr2Me2)] (3; IiPr2Me2 = 1,3-di-iso-propyl-4,5-dimethylimidazol-2-yildene) reversibly coordinates N2 to form the 17VE, low-spin (S = 1/2) compound [Cp′Fe(IiPr2Me2)(η1-N2)] (4).

Graphical abstract: Reversible dinitrogen binding to [Cp′Fe(NHC)] associated with an N2-induced spin state change

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Publication details

The article was received on 27 Feb 2017, accepted on 03 Apr 2017 and first published on 10 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC01535F
Citation: Chem. Commun., 2017, Advance Article
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    Reversible dinitrogen binding to [Cp′Fe(NHC)] associated with an N2-induced spin state change

    M. Reiners, D. Baabe, M. Zaretzke, M. Freytag and M. D. Walter, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01535F

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