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Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds

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Abstract

Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(II) complexes of type [Co(Cn-terpy)2](C12-Glu)2 (n = 15–20) have been synthesized and characterized by TEM, PXRD and magnetic susceptibility measurements. The hybrids display wire or rolled sheet supramolecular arrangements with odd and even alkyl chain dependence, with the cobalt(II) centres exhibiting gradual spin-crossover behaviours.

Graphical abstract: Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(ii) compounds

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Publication details

The article was received on 28 Feb 2017, accepted on 27 Mar 2017 and first published on 28 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01501A
Citation: Chem. Commun., 2017, Advance Article
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    Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds

    R. Akiyoshi, K. Kuroiwa, S. Alao Amolegbe, M. Nakaya, R. Ohtani, M. Nakamura, L. F. Lindoy and S. Hayami, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01501A

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