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Site-selective carbon–carbon bond formation in unprotected monosaccharides using photoredox catalysis

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Abstract

Site-selective photoredox reactions with somophiles readily enable branching of the carbon skeleton of unprotected glucosides, allosides, and xylosides regioselectively at C3. These reactions open the possibility of selective C–C bond formation in monosaccharides without multi-step protection–deprotection strategies.

Graphical abstract: Site-selective carbon–carbon bond formation in unprotected monosaccharides using photoredox catalysis

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Publication details

The article was received on 22 Feb 2017, accepted on 11 Apr 2017 and first published on 12 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC01416C
Citation: Chem. Commun., 2017, Advance Article
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    Site-selective carbon–carbon bond formation in unprotected monosaccharides using photoredox catalysis

    I. C. (. Wan, M. D. Witte and A. J. Minnaard, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01416C

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