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Transformation of the ionic liquid [EMIM][B(CN)4] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions

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Abstract

The lanthanum tetracyanoborate coordination polymers [EMIM] 1[LaNO3{B(CN)4}3(H2O)3] (EMIM = 1-ethyl-3-methylimidazolium) and 1[La(NO3)2[B(CN)4](H2O)4] mark first examples of Ln-tetracyanoborates that have been obtained in ionothermal syntheses without further solvents to influence e.g. viscosity. Thereby, the ionic liquid [EMIM][B(CN)4] is fully incorporated into product formation.

Graphical abstract: Transformation of the ionic liquid [EMIM][B(CN)4] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions

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Publication details

The article was received on 21 Feb 2017, accepted on 19 Apr 2017 and first published on 20 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC01378G
Citation: Chem. Commun., 2017, Advance Article
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    Transformation of the ionic liquid [EMIM][B(CN)4] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions

    S. H. Zottnick, M. Finze and K. Müller-Buschbaum, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01378G

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