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Issue 29, 2017
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endo-Cyclization of unsaturated RO2 radicals from the gas-phase ozonolysis of cyclohexadienes

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Abstract

Unsaturated RO2 radicals from the ozonolysis of cyclodienes can readily undergo an endo-cyclization step under atmospheric conditions forming a new ring-containing RO2 radical after further O2 addition. This path represents an extension of the atmospheric autoxidation scheme forming highly oxidized multifunctional organic compounds (HOMs). HOMs play an important role for Earth's organic aerosol burden.

Graphical abstract: endo-Cyclization of unsaturated RO2 radicals from the gas-phase ozonolysis of cyclohexadienes

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Publication details

The article was received on 20 Feb 2017, accepted on 20 Mar 2017 and first published on 20 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01350G
Citation: Chem. Commun., 2017,53, 4132-4135
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    endo-Cyclization of unsaturated RO2 radicals from the gas-phase ozonolysis of cyclohexadienes

    S. Richters, M. Pfeifle, M. Olzmann and T. Berndt, Chem. Commun., 2017, 53, 4132
    DOI: 10.1039/C7CC01350G

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