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Thiophene-fused dithiaoctaphyrins: π-system switching between cross-conjugated and macrocyclic π-networks

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Abstract

We synthesized for the first time octaphyrins with a dithieno[3,4-b:3′,4′-d]thiophene core as thiophene-fused dithiaoctaphyrins with a cross-conjugated structure. The octaphyrins revealed cross-conjugated and macrocyclic 36π-electron networks.

Graphical abstract: Thiophene-fused dithiaoctaphyrins: π-system switching between cross-conjugated and macrocyclic π-networks

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Publication details

The article was received on 17 Feb 2017, accepted on 08 Mar 2017 and first published on 17 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01273J
Citation: Chem. Commun., 2017, Advance Article
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    Thiophene-fused dithiaoctaphyrins: π-system switching between cross-conjugated and macrocyclic π-networks

    T. Higashino, A. Kumagai and H. Imahori, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01273J

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