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Phase-transfer catalyzed asymmetric synthesis of α,β-unsaturated γ,γ-disubstituted γ-lactams

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Abstract

The direct enantioselective vinylogous Michael addition of unsaturated γ-monosubstituted γ-lactams was realized by using chiral phase-transfer catalysis as a means to give enantioenriched γ,γ-disubstituted γ-lactams.

Graphical abstract: Phase-transfer catalyzed asymmetric synthesis of α,β-unsaturated γ,γ-disubstituted γ-lactams

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Publication details

The article was received on 10 Feb 2017, accepted on 31 Mar 2017 and first published on 31 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01058C
Citation: Chem. Commun., 2017, Advance Article
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    Phase-transfer catalyzed asymmetric synthesis of α,β-unsaturated γ,γ-disubstituted γ-lactams

    A. Arlt, H. Toyama, K. Takada, T. Hashimoto and K. Maruoka, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC01058C

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