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Exhaustive Suzuki–Miyaura reactions of polyhalogenated heteroarenes with alkyl boronic pinacol esters

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Abstract

A novel Suzuki–Miyaura protocol is described that enables the exhaustive alkylation of polychlorinated pyridines. This method facilitates a formal synthesis of normuscopyridine and the rapid assembly of a dumbbell shaped portion of a [2]rotaxane.

Graphical abstract: Exhaustive Suzuki–Miyaura reactions of polyhalogenated heteroarenes with alkyl boronic pinacol esters

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Publication details

The article was received on 07 Feb 2017, accepted on 28 Feb 2017 and first published on 03 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC00997F
Citation: Chem. Commun., 2017, Advance Article
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    Exhaustive Suzuki–Miyaura reactions of polyhalogenated heteroarenes with alkyl boronic pinacol esters

    S. Laulhé, J. M. Blackburn and J. L. Roizen, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC00997F

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