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Issue 28, 2017
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Palladium-catalyzed intermolecular amination of unactivated C(sp3)–H bonds via a cleavable directing group

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Abstract

Palladium-catalyzed intermolecular amination of unactivated C(sp3)–H bonds was developed. Using NFSI as both the amino source and the oxidant, this protocol operates under mild conditions with excellent terminal selectivity and a broad substrate scope. Moreover, the directing group can be easily removed to produce 1,2-amino alcohols.

Graphical abstract: Palladium-catalyzed intermolecular amination of unactivated C(sp3)–H bonds via a cleavable directing group

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Publication details

The article was received on 30 Jan 2017, accepted on 16 Mar 2017 and first published on 16 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC00808B
Citation: Chem. Commun., 2017,53, 3986-3989
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    Palladium-catalyzed intermolecular amination of unactivated C(sp3)–H bonds via a cleavable directing group

    L. Jin, X. Zeng, S. Li, X. Hong, G. Qiu and P. Liu, Chem. Commun., 2017, 53, 3986
    DOI: 10.1039/C7CC00808B

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