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Issue 28, 2017
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Entropic electrolytes for anodic cycloadditions of unactivated alkene nucleophiles

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Abstract

Unactivated alkenes were previously found to be effective carbon nucleophiles for anodic cycloadditions in lithium perchlorate/nitromethane electrolyte solution. Herein, 7Li NMR analysis and calorimetric studies clearly illustrate that the entropic effect is essential for these anodic cycloadditions, which has led to the successful screening of novel effective electrolytes.

Graphical abstract: Entropic electrolytes for anodic cycloadditions of unactivated alkene nucleophiles

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Publication details

The article was received on 24 Jan 2017, accepted on 14 Mar 2017 and first published on 14 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC00664K
Citation: Chem. Commun., 2017,53, 3960-3963
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    Entropic electrolytes for anodic cycloadditions of unactivated alkene nucleophiles

    Y. Imada, Y. Yamaguchi, N. Shida, Y. Okada and K. Chiba, Chem. Commun., 2017, 53, 3960
    DOI: 10.1039/C7CC00664K

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